Arc Welding Corrosion issues

Some materials, notably high-strength steels, aluminium, and titanium alloys, are susceptible to hydrogen embrittlement. If the electrodes used for welding contain traces of moisture, the water decomposes in the heat of the arc and the liberated hydrogen enters the lattice of the material, causing its brittleness. Electrodes for such materials, with special low-hydrogen coating, are delivered in sealed moisture-proof packagings. New electrodes can be used straight from the can, but when moisture absorption may be suspected, they have to be dried by baking (usually at 800-1000 °F) in a drying oven. Flux used has to be kept very dry as well.

Some austenitic stainless steels and nickel-based alloys are prone to intergranular corrosion. When subjected to temperatures around 700 °C for too long time, chromium reacts with carbon in the material, forming chromium carbide and depleting the crystal edges of chromium, impairing their corrosion resistance in a process called sensitization. Such sensitized steel undergoes corrosion in the areas near the welds where the temperature-time was favorable for forming the carbide. This kind of corrosion is often termed weld decay.

Knifeline attack (KLA) is another kind of corrosion affecting welds, impacting steels stabilized by niobium. Niobium and niobium carbide dissolves in steel at very high temperatures. At some cooling regimes, niobium carbide does not precipitate, and the steel then behaves like unstabilized steel, forming chromium carbide instead. This affects only a thin zone several millimeters wide in the very vicinity of the weld, making it difficult to spot and increasing the corrosion speed. Structures made of such steels have to be heated in a whole to about 1950 °F, when the chromium carbide dissolves and niobium carbide forms. The cooling rate after this treatment is not important.

Filler metal (electrode material) improperly chosen for the environmental conditions the finished parts will be subjected to can make them corrosion-sensitive as well. There are also issues of galvanic corrosion if the electrode composition is sufficiently dissimilar to the materials welded, or the materials are dissimilar themselves. Even between different grades of nickel-based stainless steels, corrosion of welded joints can be severe, despite that they rarely undergo galvanic corrosion when mechanically joined.